gadgeman method is as per his posting - the eyeometer method. Sika stalker has done a good job of explaining.
Otherwise, if you have an auto fire one shot at 25 yards. Use a reasonable sized backing board just in case you are miles out - if you are there may be a problem looming. Assuming you hit at 25 yards then holding your rifle really secure aim at your aiming mark again and then without moving the weapon adjust your scope cross hair to the bullet hole. Assuming your rifle has some grouping ability you are underway and can go to 100 yards. Or if anal fire one more at 25 yards. I boresight at home and then shoot @ 100yds no pissing around at the closer ranges - saves ammo.
Typically for say a 308 shooting 150grs and scope 1.5 centre to bore centre you should hit at 25 yards ~ 0.8" (20mm) low to be on at 100 yards.
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