As long as you're realistic about the outcome, then start them as early as you want. I made my oldest girls a little .22lr, but it is very low key stuff - just 3 or 4 shots and then it goes back in the safe before she gets too bored.
Video of .22lr V's 2L Coke bottle full of water
Sorry its upside down - can't work out how to fix it, but you get the idea. That's about all I can realistically expect from her at that age.
kj
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